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08-31
2022
High-Performance Organic Photovoltaic Modules Using Eco-Frien...
Qiang Wu,Yue Yu,Xinxin Xia,Yuhan Gao,Tao Wang,Rui Sun,Jing Guo,Shanshan Wang,Guohua Xie,Xinhui Lu,Erjun Zhou,Jie Min.Joule(闵杰) Abstract: The development of the internet-of-thing (IoT) ecosystem has an urgent demand for convenient energy sources, such as indoororganic photovoltaics(IOPVs), to power IoT devices. However, the limited medium band-gap acceptors ...
08-31
2022
Synthesis of Cyclopentene Derivatives via Electrochemically I...
Zhipeng Guan,Shuxiang Zhu,Yayu Ye,Xiangwei Li,Yanlong Liu,Pengjie Wang,Prof. Heng Zhang,Dr. Zhiliang Huang,Prof. Aiwen Lei.Angew. Chem. Int. Ed.(雷爱文,张恒,黄志良) Abstract: Cyclopentenes are common cores in many natural products, and in bioactive and functional molecules. However, their synthesis remains challenging in terms of harsh conditions, poor selectivity, ...
08-31
2022
Electrophotochemical Ce-Catalyzed Ring-Opening Functionalizat...
Zhaoliang Yang,Dali Yang,Jianye Zhang,Chenyu Tan,Jiajun Li,Shengchun Wang,Heng Zhang,Zhiliang Huang*, and Aiwen Lei*. J. Am. Chem. Soc.(雷爱文,黄志良) Abstract: Selective cleavage and functionalization of C–C bonds in alcohols is gaining increasing interest in organic synthesis and biomass conversion. In particular, the development of redox-neutral catalytic methods w...
08-31
2022
Site-selective amination towards tertiary aliphatic allylamin...
Shengchun Wang,Yiming Gao,Zhao Liu,Demin Ren,He Sun,Linbin Niu,Dali Yang,Dongchao Zhang,Xing’an Liang,Renyi Shi,Xiaotian Qi&Aiwen Lei.Nature Catalysis(雷爱文,戚孝天) Abstract: Aliphatic allylamines are widely used for the synthesis of diverse building blocks for agrochemicals and pharmaceuticals; there is therefore considerable interest in developing versatile and dir...
07-08
2022
Copper-catalyzed regio- and stereo-selective hydrosilylation ...
Shaowei Chen,Xiaoqian He,Yi Jin,Yu Lan*&Xiao Shen*.Copper-catalyzed regio- and stereo-selective hydrosilylation of terminal allenes to access (E)-allylsilanes.Nature Communications.(沈晓、蓝宇) Abstract: Regioselectivity and stereoselectivity control in hydrosilylation of terminal allenes is challeging. Although the selective synthesis of vinylsilanes, branched allylsila...
05-17
2022
Dual-Resolving of Lipid Positional and Geometric Isomers of C...
Guifang Feng, Ming Gao, Liwei Wang, Jiayi Chen, Menglu Hou, Qiongqiong Wan, Yun Lin, Guoyong Xu, Xiaotian Qi & Suming Chen.Dual-resolving of positional and geometric isomers of C=C bonds via bifunctional photocycloaddition-photoisomerization reaction system.Nat. Commun.(陈素明) Abstract: The biological functions of lipids largely depend on their chemical structures. The po...
05-04
2022
Diastereoselective Transfer of Tri(di)fluoroacetylsilanes-Der...
Yizhi Zhang,Gang Zhou,Xingxing Gong,Zhuanzhuan Guo, Xiaotian Qi, Xiao Shen.Diastereoselective Transfer of Tri(di)fluoroacetylsilanes-Derived Carbenes to Alkenes.Angew. Chem. Int. Ed.(沈晓) Abstract: Stereoselective cyclopropanation reaction of alkenes is usually achieved by metal complexes via singlet-metal-carbene intermediates. However, previous transition-metal-catal...
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